Here's a listing for the first 100 volumes. I think we're on #45 right now.

1) Spider-Man #1-10
2) Fantastic Four #1-10
3) X-Men #1-10
4) Avengers #1-10
5) Spider-Man #11-19, Annual #1
6) Fantastic Four #11-20, Annual #1
7) X-Men #11-21
8) Incredible Hulk #1-6
9) Avengers #11-20
10) Spider-Man #20-30, Annual #2
11) Uncanny X-Men #94-100, Giant-Size #1
12) Uncanny X-Men #101-110
13) Fantastic Four #21-30
14) Captain America from ToS #59-81
15) Silver Surfer #1-6
16) Spider-Man #31-40, Annual #2
17) Daredevil #1-11
18) Thor from JiM #83-100
19) Silver Surfer #7-18
20) Iron Man from ToS #39-50
21) Fantastic Four #31-40, Annual #2
22) Spider-Man #41-50, Annual #3
23) Dr. Strange from ST #110-111, 114-141
24) Uncanny X-Men #111-121
25) Fantastic Four #41-50, Annual #3
26) Thor from JiM #101-110
27) Avengers #21-30
28) Fantastic Four #51-60, Annual #4
29) Daredevil #12-21
30) Thor from JiM #111-120, Annual #1
31) X-Men #22-31
32) Sub-Mariner from TtA #70-87
33) Spider-Man #51-61, Annual #4
34) Fantastic Four #61-71, Annual #5
35) X-Men #32-42
36) Golden Age Marvel Comics #1-4
37) Uncanny X-Men #122-131, Annual #3
38) Avengers #31-40
39) Hulk from TtA #59-79
40) Uncanny X-Men #132-140, Annual #4
41) Daredevil #22-32, Annual #1
42) Fantastic Four #72-81, Annual #6
43) Captain America Comics #1-4
44) Spider-Man #62-67, Annual #5, Spectacular #1-2
45) Iron Man from ToS #51-65
46) Captain America from ToS #82-99, Cap #100
47) Sub-Mariner Comics #1-4
48) X-Men #43-53, Angel solo stories
49) Dr. Strange from Strange Tales #142-168
50) Captain Marvel from MSH #12-13, CM #1-9
51) Human Torch Comics #1-4
52) Thor from JiM #121-125, Thor #126-140
53) Fantastic Four #82-93
54) Avengers #41-50, Annual #1
55) All-Winners Comics #1-4
56) Hulk from TtA #80-101, Incredible Hulk #102
57) Tales to Astonish #1-10
58) Sgt. Fury #1-13
59) Ant-Man from TTA #27, 35-52
60) Marvel Mystery Comics #5-8
61) X-Men #54-66
62) Fantastic Four #94-104
63) Rawhide Kid #17-25
64) Captain America #101-113
65) Iron Man from Tales of Suspense #66-83
66) Human Torch from Strange Tales #101-117, Ann. #2
67) Amazing Spider-Man #68-77, MSH #14
68) Tales of Suspense #1-10
69) Thor #131-140, Annual #2
70) Avengers #51-58, King-Size Special #2, X-Men #45
71) All-Winners #5-8
72) Marvel Premiere #1-2, Warlock #1-8, Hulk #176-178
73) Marvel Boy #1-2/Astonishing #3-6/YM #24-28
74) Daredevil #33-41, Fantastic Four #73
75) Dr. Strange #169-179, Avengers #61
76) USA Comics #1-4
77) Iron Man from ToS #84-99, IM & Subby #1, IM #1
78) Incredible Hulk #103-110, Special #1
79) Subby from TtA #88-101, IM & Subby #1, Subby #1
80) Thor #141-152
81) Sub-Mariner Comics #5-8
82) Captain Marvel #10-21
83) Nick Fury from Strange Tales #135-153
84) Avengers #59-68, Marvel Super Heroes #17
85) Strange Tales #1-10
86) Amazing Spider-Man #78-87
87) Rawhide Kid #26-35
88) Human Torch Comics #5b-8
89) Daring Mystery #1-4
90) Uncanny X-Men #141-150
91) Giant-Man from TtA #53-69
92) Men's Adv. #27-28/Cap #76-78/Human T. #36-38
93) Captain America #114-124
94) Tales to Astonish #11-20
95) Captain Marvel #22-33, Iron Man #55
96) Thor #153-162
97) Sgt. Fury #14-23, Annual #1
98) Tales of Suspense #11-20
99) Captain America Comics #5-8
100) Marvel Feature #1-3, Defenders #1-5, etc.

“You and your friends better batten down the hatches because when it hits, you’re all going to wonder how you ever thought you could live so large and leave so little for the rest of us.”