Well, monthlies are probably done at a different printer than Masterworks, and these are the kind of things where each printer may have different options available to publishers. Some printers may have 8 page signatures, others 16 pages and so on. Either way I think there's a reason why all Masterworks so far have had page counts divisible by 16.

Samy wants to see the following collected editions:
X-MEN: CLAREMONT/JRJR OMNIBUS, X-FORCE OMNIBUS VOL. 2, 
NEW MUTANTS OMNIBUS VOLS. 1-2, GENERATION X OMNIBUS
PUNISHER (1987) #1-18 OHC,
PUNISHER WAR JOURNAL (1988) #1-24 OHC,
X-MEN: REVOLUTION OHC
X-TREME X-MEN VOLS. 1-2 OMNIBUS, WOLVERINE: HAMA/SILVESTRI OMNIBUS,
LEGION ARCHIVES VOL. 14, KNIGHTFALL OMNIBUS
LEGION OF SUPER-HEROES: EYE FOR AN EYE DELUXE HC